Chemicals Used by Hydraulic Fracturing Companies in Pennsylvania
Chemicals Used by Hydraulic Fracturing Companies in Pennsylvania
For Surface and Hydraulic Fracturing Activities
Prepared by the Department of Environmental Protection
Bureau of Oil and Gas Management
Compiled from Material Safety Data Sheets obtained from Industry
Clarks Summit business conducts independent testing
http://citizensvoice.com/news/clarks-summit-business-conducts-independent-testing-1.915898
Clarks Summit business conducts independent testing
BY ELIZABETH SKRAPITS (STAFF WRITER)
Published: August 2, 2010
Concern about the potential for drinking water contamination by natural gas drilling is keeping Andy Goldberg busy.
Goldberg, owner of Independent Water Testing in Clarks Summit, travels throughout Lackawanna, Luzerne, Susquehanna, Bradford and Wayne counties to do baseline testing on drinking water wells, and has had inquiries about his service from as far away as West Virginia and Michigan.
“My office is my car. I do between (600 to 800) miles a week,” he said.
Goldberg said he graduated from Harvard and worked in health care in New York for 16 years. Independent Water Testing is a new business and he’s the sole employee – so far.
“There is a huge need for the service,” he explained. “People have a lot of questions about what’s going on, what do they need to be concerned about, how to protect themselves and from what.”
Natural gas companies have been leasing land throughout Northeastern Pennsylvania, and exploratory wells are being drilled in southern Wyoming and northern Luzerne counties.
“It’s happening very fast. People have lots of questions,” Goldberg said. “I try to, in addition to providing this service, be a source of information and to help people as they educate themselves on this issue.”
Goldberg said he tests water with the three-tiered system developed by Penn State Cooperative Extension to find contaminants most likely to be caused through natural gas drilling. He uses a state-accredited laboratory.
“The business first and last revolves around making sure you can stand up in court and support the work you did .⦠to provide that backing for your homeowner against, potentially, a large gas company,” he said.
He advises homeowners to get their wells tested before any earth disturbance, and retested on an annual basis to check for problems such as bacterial contamination, which is a fairly easy fix.
Goldberg’s Web site, IndependentWaterTesting.com, has educational resources including a map showing where gas well permits were issued so people can judge how close they are and whether their homes are above or below the well site.
“Proximity is hard to address, because you might be very near a well and still not drawing water from a source affected by drilling; you might be very far away and are affected,” he said. “It’s one of those unknowns, or something you can’t be sure of. That’s why there’s a benefit a comfort baseline water testing can provide.”
Hydraulic fracturing, also called fracking, involves shooting millions of gallons of chemical-treated water thousands of feet underground to crack the shale and release the natural gas. Not only is there concern about the chemicals used in the process, but also about the deeply buried substances that surface with the drilling wastewater.
“I liken it to releasing a cork. You’re puncturing the earth, and there’s stuff that’s been down there for millions of years. There are ancient seawater deposits which are very salty and very contaminated, salty to the point of eight to 10 times saltier than typical seawater. And that comes back up in the flowback water, which is all of those brines, plus the compounds and the water and the sand that’s used in the fracking process,” Goldberg said.
“The challenge is you also don’t know how far your well is drawing water from. And depending on the contaminant, there’s the element of solubility. Some contaminants can travel with the water, others travel slower, and you just don’t know.”
Goldberg said he tests for a “comprehensive list” of things likely to identify contamination from gas drilling, including heavy metals and volatile organic compounds. Petroleum distillates are commonly used in fracking, and an elevated level of them in a water well is a “flashing red light” that indicates the need for further, more specific testing, he said.
The state Department of Environmental Protection has released a list of chemicals most commonly found in fracking solutions used in Pennsylvania, and the Penn State tiered tests can help identify contaminants from gas drilling, Goldberg said.
However, “There are only so many things you can practically test for, and economically test for,” he said.
Goldberg says he gets all kinds of customers and inquiries, from the person who has just leased mineral rights to the person who is never going to lease.
“This is a broad-based concern. I have people who call me when they’re on community water or city water or municipal water,” he said.
“They ask if they should have a baseline test. It’s hard to say because there are so many steps between the potential gas well contamination and their faucet. I don’t think it’s going to have much weight in a legal setting. My hope is that the water utilities are doing similar work to protect their water supplies.”
eskrapits@citizensvoice.com, 570-821-2072
Maintaining quality before drilling begins
http://citizensvoice.com/news/maintaining-quality-before-drilling-begins-1.915857
Maintaining quality before drilling begins
BY ELIZABETH SKRAPITS (STAFF WRITER)
Published: August 2, 2010
JACKSON TWP. – Just as individual property owners are testing their drinking water wells before natural gas drilling starts, Pennsylvania American Water Co. has established a baseline to ensure nothing affects the quality of water the company provides to its thousands of customers.
After giving The Citizens’ Voice a tour of the Ceasetown Reservoir’s filtration plant last week, Pennsylvania American Water representatives explained what the company is doing to augment its water quality monitoring to prevent contamination from natural gas drilling.
Although no gas wells are planned near the Huntsville or Ceasetown reservoirs in Jackson and Lehman townships, Encana Oil & Gas USA Inc. has leased mineral rights to land close to both reservoirs and is preparing to drill an exploratory well in Lake Township, not far from the Lehman Township border.
Pennsylvania American Water Production Manager Mark Cross said the company has met with Encana and showed the gas company maps to indicate where the reservoirs’ watershed is and where future drilling activity could affect them.
“We had a lot of conversations with them to say this is a concern to us, and we need ongoing communication, and we need to know what your plans are,” he said.
Pennsylvania American Water also shared its watershed maps with the state Department of Environmental Protection, Cross said. Although there is no legal requirement to notify water companies when drilling permits are issued, DEP will take the watershed maps into consideration, and Pennsylvania American Water is also keeping up “ongoing dialogue” with the state agency, he said.
“Our focus is we want to know what’s going on out there, we want constant communication, we want to know what is in place out there, what their mitigation measures are, what spill control and response plans they have,” Cross said. “And it’s worked very well. They’ve been very cooperative, both DEP and Encana.”
‘Constantly monitored’
When people in Ashley, Conyngham Township, Courtdale, Edwardsville, Hanover Township, Hunlock Township, Larksville, Nanticoke, Plymouth, Plymouth Township, Pringle, Salem Township, Shickshinny and Wilkes-Barre City turn on their taps, the water probably comes from the Ceasetown Reservoir, which is fed by Pikes Creek.
Pennsylvania American Water’s 70,000 customers served by the Ceasetown Reservoir have their water treated at a facility in Jackson Township. A similar facility treats the water from the nearby Huntsville Reservoir, which serves about 29,000 customers. Huntsville serves Dallas, Kingston Township, Swoyersville, West Wyoming and Wyoming.
The “raw water” from the reservoir is piped into the facility in a 42-inch main, where chemicals are added to coagulate the small particles and make them easier to remove, Cross said.
The water then goes through a series of filters, which include irregularly shaped plastic beads that gather impurities, and layers of sand and gravel. The water is treated with chlorine to disinfect it and lime to adjust the pH level, then it is sent to a series of storage tanks and pump stations for distribution to customers.
Ceasetown’s facility handles a normal flow of 9 million gallons a day, Plant Supervisor Sean Sorber said. During droughts, Harveys Creek is used as an emergency source, but that hasn’t been necessary for about 10 years, Cross said.
“Ceasetown Reservoir is a very good source, very good quality,” he said.
Cross said the water is “constantly monitored” at the plant, and physical tests are done in its lab. A sink in the lab has a series of specialized faucets, each pouring water in a different stage of treatment. Every shift at the plant runs a minimum of two series of 15 tests – about 100 a day – Sorber said.
Because of impending natural gas drilling, Pennsylvania American Water instituted an additional set of parameters, Cross said.
Several months ago full baseline testing started at Pikes Creek, Harveys Creek, the Huntsville Reservoir in several locations, and the raw and treated water at the Huntsville and Ceasetown plants, he said. The water is tested at the plant and in the watershed for substances including volatile organic compounds, methane and total dissolved solids – extremely tiny particles of minerals or organic matter.
“We ran a full series of baseline tests – VOCs, metals, methane – on all of the sources in this Luzerne, Lackawanna and Susquehanna county area that are subject to any possible drilling,” Sorber said. “So we have a good baseline of what we currently have, and those tests will be run periodically also, as activity increases.”
Conductivity tests are one way to measure the amount of total dissolved solids, or TDSs. Changing levels of TDSs could signify a lot of things, including the water is being affected by natural gas drilling. Sorber took a sample of untreated water from one of the faucets and placed a probe in the plastic cup, then checked the meter. It was normal.
“If we see something jumping up, that will be an indication for us there’s something going on. It’s a very straightforward test,” he said.
Besides monitoring and testing, Pennsylvania American Water is active in trying to get Pennsylvania legislation changed, according to PAWC Communications Director Terry Maenza.
Two things the company would like to see changed are adding a requirement for drinking water utilities to be notified of any nearby natural gas drilling permit applications, and to have the buffer zone outside which drilling is allowed increased from 100 feet to 2,500 feet.
“We’re being as vigilant as we possibly can be, just to keep an eye on what’s proposed and before activity takes place, what safeguards are going to be in place,” Maenza said.
eskrapits@citizensvoice.com, 570-821-2072
Casey slips ‘fracking’ rules into energy bill
http://citizensvoice.com/news/casey-slips-fracking-rules-into-energy-bill-1.908306
Casey slips ‘fracking’ rules into energy bill
BY BORYS KRAWCZENIUK (STAFF WRITER)
Published: July 29, 2010
A provision to require disclosure of all chemicals used in fracturing Marcellus Shale to extract natural gas could wind up as part of the scaled-down national energy bill the U.S. Senate might consider soon.
U.S. Sen. Bob Casey said he convinced Senate Majority Leader Harry Reid to fold disclosure provisions of his Fracturing Responsibility and Awareness of Chemicals Act into the energy bill.
“It’s a great breakthrough,” he said. “It’s a substantial step forward. It gives people information they wouldn’t have otherwise about what’s happening underneath their property.”
Senate leaders are hoping to pass the bill before the summer recess Aug. 6 after realizing they did not have the votes to pass a more comprehensive energy bill. Even if the smaller energy bill gets through the Senate, the House would have to pass it before President Barack Obama can sign it. Neither is assured.
Industry groups said the fracturing chemicals are already well-known to the public and state regulators and further disclosure would harm the development of natural gas.
“We fundamentally believe that regulation of hydraulic fracturing is best addressed at the state level, and we have been unable to reach a consensus with congressional advocates on how this program would be overseen by the federal government,” America’s Natural Gas Alliance said in a statement.
Congress and the federal Environmental Protection Agency are studying whether the chemicals used in hydraulic fracturing of shale contaminate drinking water.
Energy In Depth, an industry group, argues regulation should be left to states, which “have effectively regulated hydraulic fracturing for over 40 years with no confirmed incidents of groundwater contamination associated with (fracturing) activities.”
At public meetings on gas drilling, local residents regularly dispute the claim.
Though the industry argues the chemicals it uses are well known, a Times-Shamrock newspapers investigation determined that DEP scientists who analyzed spilled fracturing chemicals at a Susquehanna County well site in September found 10 compounds never disclosed on the drilling contractor’s material safety data sheet.
None of the 10 was included in a state Department of Environmental Protection list of chemicals used in fracturing, a list developed by the industry. When DEP posted a new list earlier this month, none of the 10 was on it.
Casey dismissed the industry criticism.
“That’s why I called it a substantial step forward if they’re attacking it,” he said. “If they’re feeling that this is giving information to people that they are reluctant to disclose, that’s why I think it’s an important change, and it’s progress on an issue that some would have thought would have taken years to get done.”
Casey’s legislation would amend the federal Emergency Planning and Community Right-to-Know Act, which requires employers to disclose what hazardous chemicals they use.
The amendments would require:
> Well-drilling operators to disclose to state regulators and the public a list of chemicals used in fracturing, commonly known as fracking. The requirement would cover chemical constituents but not chemical formulas whose manufacturers are allowed by law to keep the formulas secret, according to Casey’s office.
> Disclosure to be specific to each well.
> Disclosure of secret formulas or chemical constituents to doctors or nurses treating a contamination victim in an emergency.
> An end to thresholds for reporting chemicals normally required by law so all amounts of chemicals are reported.
In an analysis of the legislation, Energy In Depth said it would “chill” investment in innovations in fracturing and place “unrealistic burdens” on natural gas producers by requiring them to disclose secret chemical compounds whose composition they legally can know nothing about.
In an interview, DEP Secretary John Hanger said he welcomed the federal legislation, argued Pennsylvania already requires more disclosure than his bill and believes companies should disclose the volume and mix of chemicals they use in fracking.
bkrawczeniuk@timesshamrock.com
Wastewater tracking bill introduced
http://citizensvoice.com/news/wastewater-tracking-bill-introduced-1.908232
Wastewater tracking bill introduced
BY ELIZABETH SKRAPITS (STAFF WRITER)
Published: July 29, 2010
State Rep. Phyllis Mundy, D-Kingston, said Wednesday she is introducing legislation that would create a system for tracking and reporting the disposal of the polluted water that is a byproduct of natural gas drilling.
“My legislation would allow the public to track wastewater produced by this quickly growing industry from cradle to grave,” Mundy said in a prepared statement. “It would help promote public confidence that natural gas well operators are following the law on the treatment and disposal of wastewater, which can contain brine and chemicals.”
Companies with natural gas wells in the Marcellus Shale already have to make semi-annual production reports to the state Department of Environmental Protection. Mundy’s proposed legislation would expand that to include the wastewater from hydraulic fracturing of natural gas wells, and DEP would make the information available on its website.
Hydraulic fracturing, also called “fracking,” involves blasting millions of gallons of chemical-treated water thousands of feet underground to break up the shale and release natural gas.
Mundy explained the bill, which she worked on with Penn Future, is to ensure the chemical and salt-laden wastewater isn’t dumped where it’s not supposed to be.
“I think that’s a concern people have: where’s the water coming from, and where are they disposing of it?” she said. “Because it’s toxic and it’s polluting. We want to know where it’s going.”
Mundy previously introduced House Resolution 864, which urges Congress to pass U.S. Sen. Bob Casey’s Fracturing Responsibility and Awareness of Chemicals Act.
The FRAC Act is intended to close the “Halliburton Loophole” in the federal Safe Drinking Water Act, which exempts oil and gas companies from restrictions on hydraulic fracturing near drinking water sources. The FRAC Act would also require oil and gas companies to disclose all the chemicals in their hydraulic fracturing solutions.
Casey announced Wednesday provisions from the FRAC Act have been included in the Clean Energy Jobs and Oil Company Accountability Act, which will be considered ion the Senate floor.
“This is great. The more activity the better,” Mundy said when told about the new development. However, she noted, “There’s many a slip between introducing the legislation and getting it passed into law, at any level.”
If the Clean Energy Jobs and Oil Company Accountability Act doesn’t pass by the time the state legislature reconvenes in September, Mundy said she will urge leaders to bring her resolution up for vote, to show support for Casey’s efforts.
Mundy also sponsored two other pieces of natural gas drilling-related legislation. One is House Bill 2609, which would establish a one-year moratorium on issuing of new natural gas well drilling permits to give state officials more time to put appropriate regulations in place.
The other is House Bill 2608, which would prohibit natural gas companies from drilling horizontal wells or doing hydraulic fracturing within 2,500 feet of a drinking water source, instead of the current restriction of 100 feet.
eskrapits@citizensvoice.com, 570-821-2072
Complete coverage of natural gas drilling in Northeast Pennsylvania
http://republicanherald.com/news/gas-drilling
Gas Drilling Headlines
Let tax help responders
A fire last week at a natural gas drilling site in Susquehanna County was handled quickly and correctly by driller Chesapeake Energy and local volunteer firefighters, according to state regulators. No one was injured, there was no detectable contamination.
• Opinions differ on fiscal bill provision
• State rule targets chloride levels
• Rights drown in forced pool
• State puts natural gas drillers on notice
• DEP gas drilling violations database
• Natural gas companies aim to acquire all of Wyoming County’s mineral rights
• DEP shale chemical lists at odds over inclusion of above ground substances
Natural gas, unnatural risk: Hydrofracking endangers our water
http://www.nydailynews.com/opinions/2010/07/25/2010-07-25_natural_gas_unnatural_risk.html
Sunday, July 25th 2010
Natural gas, unnatural risk: Hydrofracking endangers our water
There is no higher priority for New York’s state and federal legislators than to put the brakes on the idea of opening areas upstate to the controversial form of natural gas drilling called hydraulic fracturing – “fracking,” for short.
While the technique has been around for 60 years, critics say the modern version of fracking is unsound, leaving broad swaths of land poisoned and polluted.
“Gasland,” an award-winning documentary that airs tonight on HBO (gaslandthemovie.com), shows communities in Pennsylvania, Colorado and elsewhere rife with sick people, animals that have lost their fur, and water so polluted that it actually ignites when a match is held near a kitchen tap.
The problem is a byproduct of modern fracking, which involves shooting millions of gallons of water and a cocktail of extraction chemicals deep underground – on average, 8,000 feet below the surface. The pressurized water and chemicals shake loose natural gas that is then captured and piped away.
Remnants of the chemicals and half of the millions of gallons of water, however, stay behind and begin rising. The tainted water can end up polluting fresh drinking water, which tends to be only 1,000 feet below the surface.
Worst of all, a mysterious process called methane migration can leak combustible gas into the water table as well. That gives some residents in fracking areas tap water that explodes on contact with an open flame.
“It’s really quite shocking and strange and, and weirdly kind of thrilling when you see it,” the director of “Gasland,” Josh Fox, told me when describing the polluted water that turns to fire. “And then all of a sudden it hits: It’s really a huge problem.”
The film shows people assembling complicated 500-gallon bottled water systems, bemoaning lost property values and complaining of brain lesions, exhaustion and other health issues.
Fox blames the problem on the so-called Halliburton loophole of 2005, provisions in that year’s Energy Policy Act that exempted gas drilling companies from the Safe Water Drinking Act of 1974 and allowed them to not disclose the 500-plus chemicals that get shot underground during fracking.
Passage of the law set off a wave of fracking that has reached 34 states. Fox himself became aware of the trend when a gas company offered him $4,000 per acre to let them frack on land he owns near Delaware – an offer that would have brought him $100,000. After studying the process and its effects around the country, Fox rejected the money outright.
His land, like all of upstate New York, sits atop a vast underground deposit of natural gas, the Marcellus Shale, that stretches from New York to West Virginia and could be a veritable Saudi Arabia of natural gas.
Hopes of exploiting these and other major gas reserves are the reason energy magnate T. Boone Pickens made TV ads advocating more extraction of “clean, natural gas” to wean America off of foreign oil. Pickens was persuasive, patriotic and profit-driven. I just hope he plans more commercials to explain the potential of frack-induced pollution.
A growing number of people are already saying: Not so fast. The New York City Department of Environmental Protection has warned that fracking near the upstate watershed could pollute the drinking water for the 16 million people who live in or near our city.
Environmental groups are calling for a moratorium on leasing any land in New York for fracking, and Albany is considering a law imposing a one-year moratorium on fracking. A federal bill would give the federal Environmental Protection Agency the power to regulate fracking.
These are all good starts at what must be a top priority for elected officials: saving New York from environmental horrors that have already shown much of America the false promise of fracking.
elouis@nydailynews.com
Shale drilling, what is it?
http://www.tnonline.com/node/118669
Shale drilling, what is it?
Reported on Friday, July 23, 2010
By MICHAEL NEWTON TN Correspondent tneditor@tnonline.com
A lack of knowledge among citizens of Carbon County about the issue of shale drilling is seen as a major problem by the Kidder Township Environmental Advisory Committee. < http://www.americantowns.com/pa/lakeharmony/events/environmental-advisory-council >
“People have no idea,” said committee member Bob Dobosh at the EAC’s meeting this week.
This lack of knowledge is seen as a problem because choices made about shale drilling will have an immense impact on the future of both the state and the nation. Debate has raged between proponents, who view it as a vital part of the nation’s energy plan, and detractors who fear that the environmental impacts are not properly understood.
Shale drilling is a complex process and the technological advances that have made it possible have outpaced research into its consequences.
“Nobody is asking the question of what happens 10 years from now when we’re out of water,” said EAC member Hank George.
It is currently believed that there is more than 363 trillion cubic feet of harvestable gas in the Marcellus shale bloom. That is enough to supply all of the nation’s energy needs for 15 years. A typical well located on an 80-acre space, is expected to produce around 2.5 billion cubic feet of gas over the course of its operations. The gas is found in small cracks and fissures running through the porous rock.
The process of extracting the gas is complicated and relies primarily on two techniques hydrofracing and horizontal drilling. Hydrofracing is a process where a ‘mud’ made out of water and chemicals, is shot down into the well in order to break up the shale and allow the gases in between cracks in the rock to flow to the surface. Horizontal drilling is a process whereby the well is slowly turned at a 90 degree angle. Using horizontal drilling, a typical well can extract gas in a radius of over a mile.
According to a report issued by the United States Geological Society, shale drilling presents three main areas of concern over water quality. The first is the massive amount of water needed to perform hydrofracing. Each round of hydrofracing can use up to 3 million gallons of water. Thus, concerns have risen among local municipal water authorities as to where all that water will come from. If too much is used from local water sources, they can be damaged or depleted, leading to unnatural drought conditions.
The shipment of water and materials in extremely heavy trucks over small mountain roads may lead to erosion, which could further damage water tables. In addition, there is no way to know exactly how much material and chemicals will leak out of the trucks over time.
Once the hydrofracing solutions have been used they must be properly disposed. A typical 3-million gallon hydrofracing job can be expected to produce at least 15,000 gallons of contaminated water. Not only is the solution full of chemicals, many of which are guarded company secrets, but being in contact with rock formations means that when the solution comes to the surface, it brings along large amounts of silt and possibly harmful minerals. This presents difficulties because water treatment plants are not able to adequately remove these contaminants. Several alternative solutions have been proposed, such as reinjecting the hydrofracing solutions into shallow pits, but there is no clear consensus or across the board standard.
Knowledge about the process of shale drilling and the issues that go along with it can help citizens make informed decisions about the future of the state. Toward that end, the Kidder EAC is going to prepare informational newsletters and distribute them to the various homeowners’ associations in the websites.
Local zoning is perhaps best control over Marcellus play, planner says
Local zoning is perhaps best control over Marcellus play, planner says
With Pennsylvania’s Marcellus shale-gas epoch still in its infancy, some experts doubt we have seen one-tenth of what is yet to come and recommend that municipalities brace themselves for rapid change. “People who are not in the Marcellus areas have no clue how big this is going to be,” said Kurt Hausammann Jr., planning director for Lycoming County. “This has the possibility to change our whole way of life.”
Read the full story on Live: http://live.psu.edu/story/47431/nw69
Download This Story Here
Local zoning is perhaps best control over Marcellus play, planner says
Marcellus Shale Regulations Regarding Drinking Water in PA
Bryan Swistock, Penn State Water Quality Extension Specialist, discusses the Marcellus shale regulations regarding drinking water in PA.